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Add logical to allow for the fixing the duplicate heterogeneous chemistry reactions in UKCA StratTrop and CRI-Strat2 schemes #432

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@theabro

Are there any linked Issues or Pull Requests?

MetOffice/um#61 / MetOffice/um#71
MetOffice/ukca#30 / MetOffice/ukca#32

Brief description

Within UKCA, N2O5 hydrolysis

N2O5 + H2O --> HONO2 + HONO2

is actually covered by 2 separate reactions, H04 and B85. There is actually considerable overlap of these reactions in the troposphere, leading to overcounting.

A fix is to ensure, using the tropospheric mask, that only H04 works in the stratosphere and B85 only works in the troposphere.

This will be controlled with a temporary logical and changes are required to the UKCA (MetOffice/ukca#30) to account for this. This issue was originally identified by Dr Yao Ge (@yg460-cam) in Cambridge and she provided the original code changes at UM13.9.

Further details of the issue.

Initially the logical, l_fix_ukca_n2o5_h2o, will be hard-coded to .false. in the UKCA interface, as this fix is targetting UKESM2. Later changes will be made to allow for this logical to be passed via namelist.

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Linked UKCAThis PR is linked to a MetOffice/ukca PRLinked UMThis PR is linked to a MetOffice/um PRbugSomething isn't workingcla-modifiedThe CLA has been modified as part of this PR - added by GAcla-signedThe CLA has been signed as part of this PR - added by GA

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